The set is a triple album of every Rolling Stones single—and their B-Sides—mostly in their original mono mixes (at least as of the 2002 reissue), in both the UK and US encompassing their entire era with Decca Records in the United Kingdom and London Records in the United States—hence the album's title.
The original collection was produced by Andrew Loog Oldham, and digitally compiled and prepared under his supervision by P. D. Rain and Jody Klein.
With a range from 1963 to 1971, the set begins with their very first UK single, Chuck Berry's "Come On", and runs to Sticky Fingers' "Brown Sugar" and "Wild Horses" (which Allen Klein shares release rights with The Rolling Stones).