The track list was officially announced on the Neil Young Archives site on September 20, 2020, with the first single, "Come Along and Say You Will", being posted to the site as the Song of the Day on October 14. The set then went up for pre-order on October 16, 2020 as an exclusive release to his online store, with only 3,000 copies being initially made available worldwide. After selling out the following day, Young announced several weeks later that a general retail version, as well as a second pressing of the deluxe box set, is expected to be released to market on March 5th, 2021. This was followed by the release of a second single, "Homefires", on October 21, and a third, an alternate version of "Powderfinger", on November 3.
Of the 131 tracks on the track listing, 63 are previously unreleased. These include live and alternate versions of previously released songs. Twelve of the songs on this set have never been released in any form.
Disc 1 - Everybody's Alone (1972-1973)
Disc 2 - Tuscaloosa (1973)
Disc 3 - Tonight's The Night (1973)
Disc 4 - Roxy: Tonight's The Night Live (1973)
Disc 5 - Walk On (1973-1974)
Disc 6 - The Old Homestead (1974)
Disc 7 - Homegrown (1974-1975)
Disc 8 - Dume (1975)
Disc 9 - Look Out For My Love (1975-1976)
Disc 10 - Odeon Budokan (March 1976)
* = previously unreleased song
** = new unreleased version
Disc 1 - Everybody's Alone (1972-1973) - 46.26:72
01. Letter From 'Nam *
02. Monday Morning **
03. The Bridge **
04. Time Fades Away **
05. Come Along And Say You Will *
06. Goodbye Christmas On The Shore *
07. Last Trip To Tulsa
08. The Loner **
09. Sweet Joni *
10. Yonder Stands The Sinner
11. L.A. (Story)
12. L.A. **
13. Human Highway **
Disc 2 - Tuscaloosa (1973) - 52.27:57
01. Here We Go In The Years
02. After The Gold Rush
03. Out On The Weekend
04. Harvest
05. Old Man
06. Heart Of Gold
07. Time Fades Away
08. Lookout Joe
09. New Mama
10. Alabama
11. Don't Be Denied
Disc 3 - Tonight's The Night (1973) - 45.55:83
01. Speakin' Out Jam **
02. Everybody's Alone **
03. Tired Eyes
04. Tonight's The Night
05. Mellow My Mind
06. World On A String
07. Speakin' Out
08. Raised On Robbery *
09. Roll Another Number
10. New Mama
11. Albuquerque
12. Tonight's The Night Part II
Disc 4 - Roxy: Tonight's The Night Live (1973) - 59.15:14
01. Intro
02. Tonight's The Night
03. Roll Out The Barrel
04. Mellow My Mind
05. World On A String
06. Band Intro
07. Speakin' Out
08. Candy Bar Rap
09. Albuquerque
10. Perry Como Rap
11. New Mama
12. David Geffen Rap
13. Roll Another Number (For The Road)
14. Candy Bar 2 Rap
15. Tired Eyes
16. Tonight's The Night - Part II
17. Walk On
18. The Looing End (When You're On) **
19. Outro
Disc 5 - Walk On (1973-1974) - 47.48:65
01. Winterlong
02. Walk On
03. Bad Fog Of Loneliness **
04. Borrowed Tune
05. Traces **
06. For The Turnstiles
07. Ambulance Blues
08. Motion Pictures
09. On The Beach
10. Revolution Blues
11. Vampire Blues
12. Greensleeves *
Disc 6 - The Old Homestead (1974) - 70.44:05
01. Love/Art Blues **
02. Through My Sails **
03. Homefires *
04. Pardon My Heart **
05. Hawaiian Sunrise **
06. LA Girls And Ocean Boys *
07. Pushed It Over The End **
08. On The Beach **
09. Vacancy **
10. One More Sign **
11. Frozen Man *
12. Give Me Strength **
13. Bad News Comes To Town **
14. Changing Highways **
15. Love/Art Blues **
16. The Old Homestead
17. Daughters *
18. Deep Forbidden Lake
19. Love/Art Blues **
Disc 7 - Homegrown (1974-1975) - 35.20:93
01. Separate Ways
02. Try
03. Mexico
04. Love Is A Rose
05. Homegrown
06. Florida
07. Kansas
08. We Don't Smoke It No More
09. White Line
10. Vacancy
11. Little Wing
12. Star Of Bethlehem
Disc 8 - Dume (1975) - 65.01:00
01. Ride My Llama **
02. Cortez The Killer
03. Don't Cry No Tears
04. Born To Run *
05. Barstool Blues
06. Danger Bird
07. Stupid Girl
08. Kansas **
09. Powderfinger **
10. Hawaii **
11. Drive Back
12. Lookin' For A Love
13. Pardon My Heart
14. Too Far Gone **
15. Pocahontas **
16. No One Seems To Know **
Disc 9 - Look Out For My Love (1975-1976) - 58.45:51
01. Like a Hurricane
02. Lotta Love
03. Lookin' For A Love
04. Separate Ways **
05. Let It Shine **
06. Long May You Run
07. Fontainebleau
08. Traces **
09. Mellow My Mind **
10. Midnight On The Bay **
11. Stringman **
12. Mediterranean *
13. Ocean Girl **
14. Midnight On The Bay **
15. Human Highway **
Disc 10 - Odeon Budokan (March 1976) - 44.00:59
01. The Old Laughing Lady **
02. After The Gold Rush **
03. Too Far Gone **
04. Old Man **
05. Stringman **
06. Don't Cry No Tears **
07. Cowgirl In The Sand **
08. Lotto Love **
09. Drive Back **
10. Cortez The Killer **
